Product ID:GLACIAL ACETIC ACID
MSDS Date:01/10/1990
FSC:6810
NIIN:00-222-2634
MSDS Number: BKQTC

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 716-722-5151

Preparer: DOD-HMIS

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

ACETIC ACID (SARA III)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 100%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 3310 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MATERIAL IS A CORROSIVE ACID SOLUTION
AND WILL CAUSE IRRITATION AND BURNS TO EYES, SKIN, RESPIRATORY
TRACT AND GASTROINTESTINAL TRACT. INGESTION WILL RESULT IN BURNS TO
THE MOUTH, THROAT, A GASTROINTE STINAL TRACT. CHRONIC: PROLONGED
EXPOSURE MAY LEAD TODELAYED EFFECT INCLUDING SCARRING AND INFECTION
OF LIVER/KIDNEY
Explanation of Carcinogenicity:ACETIC ACID IS NOT LISTED BY IARC, NTP
OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE AND SKIN BURNS DEVELOP
IMMEDIATELY.INGESTION MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING,
HEMORRAGING, AND PERFORATION OF ORGANS. VAPOR IS IMMEDIATELY
IRRITATING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WAT FOR 15 MINUTES. GET
MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WAS WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF
BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF VICTIM
ISNOT BREATHING. INGESTIO DO NOT INDUCE VOMITING. GIVE VICTIM LARGE
AMOUNTS OF WATER TO DILUTE MATERIAL.GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:=39.4C, 103.F
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSE CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, ELIMINAT SOURCES OF
IGNITION, AND VENTILATE AREA AS REQUIRED. ABSORB SMALL SPILL WITH
INERT MATERIAL (SAW DUST, SAND, OIL DRY ETC.) PLACE WASTE IN DOT
APPROVED CONTAINER FOR DISPOSAL.
Neutralizing Agent:SODA ASH OR SODIUM BICARBONATE (SMALL SPILLS)

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER CLOSED WHEN NOT
USE. PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:CORROSIVE MATERIAL - AVOID CONTACT WITH SKIN, EYES,
AND CLOTHING. AVOID BREATHING VAPORS. "EMPTIED" CONTAINERS STILL
CONTAIN PRODUCT RESIDUE - TREAT AS HAZARDOUS.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND
NIOSH-RESPIRATOR SELECTION.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Protective Gloves:ACID RESISTANT IMPERMEABLE GLOVES
Eye Protection:FULL-FACED RESPIRATOR, IF NEEDED
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. IMPERMEABLE
BOOTS AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
MSDS COPIED FROM ONE OF THE SAME SUPPLIER SAME MATERIAL.

HCC:F6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=118.3C, 245.F
Melt/Freeze Pt:=16.7C, 62.F
Vapor Pres:11.4
Vapor Density:2.1 AIR=1
Spec Gravity:1.02
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID WITH PUNGENT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, AMINES, ALL BASES (ALKALIS)
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL,STATE AND LOCAL REGULATIONS. DILUTED AND NEUTRALIZED
MATERIAL CAN PROBABLY BE FLUSHED TO WASTE WATER TREATMENT VIA A
SEWER. UNUSED WASTE MATERIAL W OULD BE A HAZARDOUS WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.